Product ID:SUNNEN SPRAY PAINT LBB-90438
MSDS Date:08/15/1987
FSC:8010
NIIN:00F019145
MSDS Number: BLPMR

SUNNEN PRODUCTS COMPANY

7910 MANCHESTER AVENUE
ST LOUIS, MO 63143

Emergency Phone: (314) 781-2105

Info Phone: (314) 781-2105

Preparer: TERRY HELLER

Cage: 58436

SUNNEN PRODUCTS CO

SAINT LOUIS, MO 63143-2712 US

Telephone: 314-781-2100

Cage: 58436

DIACETONE ALCOHOL (4-HYDROXY-4-METHYL-2-PENTANONE)

CAS: 123-42-2

RTECS: SA9100000

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM; 9192

ISOBUTANE, 2-METHYLPROPANE

CAS: 75-28-5

RTECS: TZ4300000

OSHA PEL 1800 MG/CUM

ACGIH TLV: 1000 PPM

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT; 9192

BUTANE

CAS: 106-97-8

RTECS: EJ4200000

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM; 9192

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ISOPROPYL ALCOHOL (SARA III)

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 400 PPM/500 STEL

ACGIH TLV: 400 PPM/500STEL;9192

METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)

CAS: 78-93-3

RTECS: EL6475000

OSHA PEL 200 PPM/300 STEL

ACGIH TLV: 200 PPM/300STEL 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-BUTOXYETHANOL

CAS: 111-76-2

RTECS: KJ8575000

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9293

N-BUTYL ALCOHOL (SARA III)

CAS: 71-36-3

RTECS: EO1400000

OSHA PEL 100 PPM

ACGIH TLV: S, C 50 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ISOBUTYL KETONE (SARA III)

CAS: 108-10-1

RTECS: SA9275000

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

LEAD CHROMATE, CR, CHROME GREEN, CHROME YELLOW (SUSPECTED

CAS: 7758-97-6

RTECS: GB2975000

OSHA PEL 0.5 MG/CUM PB

ACGIH TLV: 0.05 MG/CUM CR (A2)

ACETONE (SARA III)

CAS: 67-64-1

RTECS: AL3150000

OSHA PEL 1000PPM

ACGIH TLV: 750PPM/1000STEL;9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: DAMAGE. INHALATION:
RESPIRATORY TRACT IRRITATION, NERVOUS SYSTEM DEPRESSION; NOSE,
MUCOUS MEMBRANES, LUNGS, THORAX, LIVER, KIDNEYS, BRAIN, CENTRAL
NERVOUS SYSTEM DAMAGE, RESPIRATORY IMPAIRM ENT, COMA & FATAL.
INGESTION: HARMFUL &FATAL.
Explanation of Carcinogenicity:LEAD CHROMATE IS A SUSPECTED HUMAN
CARCINOGEN BY ACGIH.
Effects of Overexposure:EYES/SKIN: DAMAGE. INHALATION: RESPIRATORY
TRACT IRRITATION, NERVOUS SYSTEM DEPRESSION; NOSE, MUCOUS
MEMBRANES, LUNGS, THORAX, LIVER, KIDNEYS, BRAIN, CENTRAL NERVOUS
SYSTEM DAMAGE, RESPIRATORY IMPAIRM ENT, COMA & FATAL. INGESTION:
HARMFUL &FATAL.
Medical Cond Aggravated by Exposure:RESPIRATORY IMPAIRMENT SUCH AS
EMPHYSEMA.

First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN:
WASH THOROUGHLY W/MILD NON-ABRASIVE SOAP & WATER. INHALATION:
REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. INGESTION: OBTAIN MEDICAL
ATTENTION IN ALL CASES.

Flash Point Method:TOC
Flash Point:-25F
Lower Limits:0.9%
Upper Limits:12.8%
Extinguishing Media:FOAM, CO, DRY CHEMICAL & WATER FOG
Fire Fighting Procedures:WEAR SELF-CONTAINED RESPIRATORY EQUIPMENT.
WATER SPRAY TO COOL THE CONTAINERS DURING FIRE CONDITIONS MAY HELP
PREVENT RUPTURE.
Unusual Fire/Explosion Hazard:EXPOSURE TO TEMPS. >120F MAY CAUSE THE
CONTAINER TO BURST, RELEASING THE HIGHLY FLAMMABLE PROPELLANT.
PROPELLANT VAPORS ARE >AIR.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. VENTILATE AREA.
ABSORB LIQUID W/INERT MATERIAL USING NON-SPARKING TOOLS. IF CAN
DEVELOPS A LEAK, MOVE IT OUTSIDE.

Handling and Storage Precautions:ELMINATE IGNITION SOURCES. USE GOOD
VENTILATION. DON'T SMOKE OR USE CONTACT LENSES. DON'T PUNCTURE CAN.
DON'T SMOKE.
Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING &
INHALING THE CONTENTS OF THE AEROSOL CAN BE HARMFUL OR FATAL. A
DEFORMED CONTAINER HAS REDUCED EXPANSION SPACE & MAY DEVELOP
DANGEROUS PRESSURE CAUSI NG IT TO BURST, DON'T USE.

Respiratory Protection:USE APPROVED AIR-PURIFYING RESPIRATOR. IF >TLV
USE AN APPROVED POSITIVE PRESSURE SELF-CONTAINER BREATHING
APPARATUS.
Ventilation:USE MECHANICAL VENTILATION TO KEEP Protective Gloves:RECOMMENDED
Eye Protection:GOGGLES
Work Hygienic Practices:WASH HANDS AFTER USE.
Supplemental Safety and Health
EVAPORATION RATE: RELATIVE TO BUTYL ACETATE OR ETHER: PROPELLENTS IS
FASTER. SOLVENT IS SLOWER.

Boiling Pt:B.P. Text:<0F
Vapor Density:>AIR
Evaporation Rate & Reference:SEE SUPP
Solubility in Water:<0.1%
Appearance and Odor:COLORED LIQUID W/SOLVENT ODOR
Percent Volatiles by Volume:91%

Stability Indicator/Materials to Avoid:YES
PEROXIDES, STRONG OXIDIZING AGENTS SUCH AS CHLORINE, PERMANGANATES &
DICHROMATES
Stability Condition to Avoid:TEMPS. >120F, SPARKS, HEAT & OPEN FLAME
Hazardous Decomposition Products:CO, CO2, LEAD & NITROGEN

Waste Disposal Methods:DON'T INCINERATE AS CONTAINERS MAY EXPLODE OR
DISCARD IN COMPACTOR AS CONTENTS MAY BE RELEASED IN A DANGEROUS
MANNER. DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL
REGULATIONS. DON'T PUNCTURE CAN.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.